On August 17, 2006, to further promote the album, Brown began his major co-headlining tour, The Up Close and Personal Tour.
In 2008, Brown began work on his-then upcoming third studio album.His second album Exclusive (2007) spawned his second Hot 100 number one "Kiss Kiss", in addition to "With You" and "Forever". Alongside his work in the music industry, Brown has pursued an acting career.The album was also certified double platinum by the RIAA. In 2007, he made his on-screen feature film debut in Stomp the Yard, and appeared as a guest on the television series The O. Other films Brown has appeared in, include This Christmas (2007), Takers (2010), Think Like a Man (2012), and Battle of the Year (2013)."Kiss Kiss", featuring and produced by T-Pain, was released as the album's second single.It reached number one on the US Billboard Hot 100 chart, and became Brown's second number one single following "Run It! "With You", a song produced by Stargate, was released as the third single from Exclusive, and reached number two on the US Billboard Hot 100 chart.